Polar Stratospheric Clouds (PSCs) photographed in Sweden http://earthobservatory.nasa.gov/IOTD/view.php?id=622 |
mechanisms of chemical ozone depletion are that low temperatures in the stratosphere (high in the atmosphere!) in the Arctic encourage the formation of Polar Stratospheric Clouds (see picture) made up of water vapour and Nitric Acid (HNO3). These clouds and other aerosols provide surfaces for the conversion of Chlorine into reactive forms such as Chlorine Monoxide (ClO) which act as catalysts for Ozone removal. It's this chemical process that is thought to be behind the large reduction in Ozone concentrations in the Stratosphere during the 2010-11 winter.
This process usually only lasts around 2-3 months in the Arctic when the temperatures are cold enough. During the 2010-11 winter however, an unusually strong polar vortex in the Stratosphere meant colder conditions lasted for much longer, around 4 months, a similar pattern to the Antarctic which has a large Ozone 'hole' during the winter. This led to an unprecedented level of 'Chlorine activation' as described above, including Chlorine Monoxide. Shown in the graph below as the thick red line, 2011 high ClO levels stuck around long after levels declined in previous 'cold' years (eg 2004-5 shown in Orange) and chlorine was only 'deactivated' in mid-March compared to February in 'normal' years. It seems to follow patterns of typical Antarctic ClO levels (shown in dark grey) more closely than Arctic patterns (light grey), strongly suggesting it was this chemical process that caused the low levels of ozone in 2011.
Stratospheric Ozone (O3) levels during the Arctic 2010-11 winter. Key as above. Direct from Manney et al 2011. |
Direct from Manney et al 2011 |
Is it likely to happen again though? It's possible that what happened this year was a 'perfect storm', when all the factors combined to cause this anomaly. There are suggestions that greenhouse gas emissions may be causing a rise in these events, firstly by altering atmospheric composition and therefore it's radiative properties which affect Stratopheric vortex formation, and secondly by cooling the stratosphere itself. Stratospheric temperatures have been dropping over the last 30 years or so on average, a trend I found surprising. Also, the fact that this ozone event happened with temperatures not much colder than previous years makes a repeat more likely. That being said, temperature is not the only factor, as we've seen; duration of temperature is likely just as important.
It's difficult to say what really caused this anomaly to be so much worse than during other 'cold' winters, and it's even more difficult to model and predict, so it's likely we'll only know of such an event after it happens. After looking into it, though, I'm not convinced it's a great threat, and is unlikely to be on the same scale as other climate change induced threats. As always, more study is required!
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*On a side note, I'd really encourage you to follow the link and check out the interactive pdf version available under 'pdf options', it looks like a great way to include supplementary info and links to related articles
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